Poly[[[diisothiocyanatocobalt(II)]-bis[μ-4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol]] dimethylformamide disolvate dihydrate]

Poly[[[diisothiocyanatocobalt(II)]-bis[μ-4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol]] dimethylformamide disolvate dihydrate]

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In the title compound, {[Co(NCS)2(C16H20N6O)2]·2C3H7NO·2H2O}n, each CoII ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis(1,2,4-triazol-1-ylmethyl)phenol (L) ligands, and by two N atoms Stock from two axial thiocyanate anions [Co—N = 2.104 (3)–2.144 (3) Å].

The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane.The dimethylformamide and solvent water molecules participate in intermolecular O—H.O and O—H.

S hydrogen bonds, Tools which consolidate the crystal packing.